Charge Distributions and Chemical Effects

Name: Charge Distributions and Chemical Effects
Brand: Springer
SKU: 1-99-539-000308
Price: 54.99 USD
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"Charge Distributions and Chemical Effects" by S. Fliszar is a astronomy book and space science reference focused on Cosmology. Best for students, researchers, and serious astronomy enthusiasts.

The energy of a molecule can be studied with the help of quantum theory, a satisfactory approach because it involves only basic and clearly identified physical concepts. In an entirely different approach, the molecular energy can be broken down into individual contributions reflecting chemical bonds plus a host of subsidiary "effects", like y-gauche, skew pentane, ring-strain, etc. , giving an overall picture in terms of topological characteristics. The latter approach can be successful, particularly if a sufficient number of particular topological situations have been parametrized (which is an empir ical way of "understanding" chemistry), but also contains the seed for difficulties. Indeed, the danger exists of unduly ascribing a physical meaning to corrective terms whose function is primarily to account in an empirical fashion for discrepancies between "expected" and observed results. The link between this type of empirical approach and the knowledge that the ground state energy is uniquely determined by the electron density is lost somewhere along the road, although some of the "steric effects" are here and there vaguely traced back to electronic effects. The approach presented in this monograph goes back to the fundamen tals in that it is exclusively based on interactions involving nuclear and electronic charges. Confining the study to molecules in their equilibrium geometry, the problem of molecular energies is reduced to its electrostatic aspects, explicitly involving local electron populations.

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Best For: Advanced students and researchers in physics, chemistry, and biochemistry focusing on molecular energy and electronic structure.

Focus: Exploring molecular energy through quantum theory and chemical bond contributions.

Covers: Quantum theory applications to molecular energy, chemical bond analysis, and subsidiary chemical effects such as y-gauche and ring-strain.

Why It Matters: Provides a detailed framework linking quantum theory with chemical bonding and molecular energy, aiding deeper understanding of molecular structure and interactions.

"Charge Distributions and Chemical Effects" by S. Fliszar is a astronomy book and space science reference focused on Cosmology. Best for students, researchers, and serious astronomy enthusiasts.

Topic: Cosmology

Author: S. Fliszar

Who this is for:

Astronomy students
Researchers and advanced hobbyists
Readers exploring space science topics

Why this book matters: It matters because it helps readers build a stronger understanding of astronomy concepts, observations, and scientific ideas related to space.

The energy of a molecule can be studied with the help of quantum theory, a satisfactory approach because it involves only basic and clearly identified physical concepts. In an entirely different approach, the molecular energy can be broken down into individual contributions reflecting chemical bonds plus a host of subsidiary "effects", like y-gauche, skew pentane, ring-strain, etc. , giving an overall picture in terms of topological characteristics. The latter approach can be successful, particularly if a sufficient number of particular topological situations have been parametrized (which is an empir ical way of "understanding" chemistry), but also contains the seed for difficulties. Indeed, the danger exists of unduly ascribing a physical meaning to corrective terms whose function is primarily to account in an empirical fashion for discrepancies between "expected" and observed results. The link between this type of empirical approach and the knowledge that the ground state energy is uniquely determined by the electron density is lost somewhere along the road, although some of the "steric effects" are here and there vaguely traced back to electronic effects. The approach presented in this monograph goes back to the fundamen tals in that it is exclusively based on interactions involving nuclear and electronic charges. Confining the study to molecules in their equilibrium geometry, the problem of molecular energies is reduced to its electrostatic aspects, explicitly involving local electron populations.